12/14/2008 Entry: "I'm dumb now?" I've moved about 20-30 potted plants into my school. Mostly clones. I'm going to name them after different disease causing microorganisms via sharpie on the pot and then give the kids extra credit if they can figure out what disease they cause. I'm also going to start a "Microbe of the Week" education project, mainly because I think they are cool. We had our second snow day today. Lame. I'm not getting paid. We may have another one tomorrow. As for the thought experiment - props to Jessica for being the only one to try. She's close enough. 50 pts to Jessica and she is now in the lead. The question was: I place a bowl of water into vacuum chamber with a straw going from the water to outside the chamber. The straw is, for now, capped. A vacuum is applied to the chamber. The answer is: "Maybe" Click the "more" for why.
A conventional understanding of how air pressure works and the knowledge that nothing "sucks" in science - that you can only push or pull - would lead someone to answer "no." Normally when using a straw 14.6 psi of air pressure is pushing down on the liquid, and when you make a partial vacuum in your mouth that 14.6 psi pushes the water into your mouth. In a vacuum that air pressure is gone, and thus there would be no pressure to push the water into your mouth. BUT, it's not that simple. You see, water in a vacuum will first boil, and then eventually freeze. You can watch it happen on youtube. This complicates things. It has to do with vapor pressure and evaporation. The temperature of a liquid that you take with a thermometer is the average temperature of all the molecules of that liquid. The individual molecules can have less or more energy, and are constantly passing energy back and forth as they collide. This transfer near the top is very one side (think crowd surfing vs moshing) and the top molecules get a lot of energy (heat) and eventually take off. This is evaporation and how water turns to gas without boiling. The lower the air pressure, the less energy is necessary for this to happen. Liquids also have a "vapor pressure" at different temperatures. It's on a logarithmic scale, increasing as it gets hotter. The vapor pressure for water at 100 deg C. is 14.6 psi, or the same as the pressure of the atmosphere. This is why water boils at that temperature - liquids boil when their vapor pressure meets or exceeds the pressure of the gasses surrounding them. The vapor pressure of water at 25 deg C (room temp) is considerably less than 14.6 psi, so it doesn't boil. But, if you apply a vacuum that water will boil, since it's vapor pressure will exceed the pressure surrounding it. IF the water does not all boil away it will probably freeze. Why? Well, as those hotter molecules are flying off the average temperature of the liquid is dropping. Eventually it will drop to zero. This is the idea behind evaporative cooling - something you do when you sweat. But lets say you apply heat, or it's warm enough for the water to not freeze right away. Eventually the vacuum will equal out. (assuming you aren't still sucking out of the chamber - which is how most vacuums are maintained) If you don't run out of water and the liquid doesn't freeze the pressure of the vaporized water in the chamber will eventually equal the vapor pressure of the water at that temperature and the liquid will reach equilibrium and stop boiling. If you can then lower the pressure in your mouth to below the vapor/gas pressure you will be able to draw water out of the chamber. Raise your hand if that made sense... 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